Okay, temps and humidity sound good. I'm not sure what type of thermometer/hydrometer the exoterra is but if it's an analog one I would replace it, they are crazy inacurite and digital are much more reliable. I'm not sure about the clay but I would replace the substrate with cypress or the coconut mulch or something like that for humidity, aspen molds easier with spraying and doesnt hold humidity well I've heard. Adding some moss and putting a damp rag on top of the hot hide will help with humidity as well.
The pot would be good, I also would recommend the reptile basics hides as they are quiet nice and cheap but you do have to pay for shipping and wait for them so it's up to you. Just make sure you get a hide that fits him snuggly and move up in size as he grows, they like to feel really secure. To help him feel better in the meantime you can put some paper towels or newspaper in the hides and cover of the back of the log with either papers towels or those little plants you have
Rat pups are totally fine. There isn't really too much difference in the two other then size really but it's generally better to get them on rats as soon as you can as when they are older and bigger it would take mulitiple mice to make the meal one day would and some snakes will get on mice and never want to switch to rats.
I think I touched on all the questions, also wanted to say welcome! Also don't worry, I was originally planning on getting a crested gecko until I met my first ball python and fell in love then all plans changed! As long as you do you research (Which it seems you have) and do everything to give the animal a good life then you'll be fine! You've come to a great place to learn
Edit: Oops looks like Zina beat me to the punch! Lol
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