I started putting hats on my boa about two years ago, and she now has a couple thousand followers, many of which are not snake people. It's actually been really positive because it's gotten a lot of people who previously hated snakes to reconsider. I really think that when done carefully it can be a huge way to reach out and educate people. She has changed many many minds.
I either just set them on her head carefully, or else use a tiny bit of peanut butter. I see no reason why it would be an issue. I clean it off gently as soon as I'm done taking pictures. Figment is a very tolerant snake.
Here are a few of my favorites.
And the one that started it all...
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