I've only hatched snake eggs, & only with vermiculite, so I can't tell you much- only that vermiculite holds more water than perlite, & whether that was the real reason for the mold, or it was just a coincidence, I can't say. Most of us try things, & we stick with them when they work for us- your experience with the same things may be totally different.
Just like 2 cooks can follow the same recipe & their food turns out differently. Maybe she used too much water with the vermiculite & the eggs drowned, then molded. Impossible to know what went wrong there. It's often recommended to measure the water added but after the first time, I never did- I just always went by "feel" & did quite well. (I usually cook the same way.)
I wouldn't make any assumptions about the other egg, much less future clutches- I don't think I've ever had a clutch that hatched 100%. Nature just isn't perfect.