Our biggest female is friendly and gentle. Our sexuality mature (but not full grown) Male is a complete psycho. Our sub adult western female tries to eat everything in front of her.
Admittedly I do not handle them enough to give you a true example of their potential. I am confident if you had any of the three as a pet and handled them regularly they would be super easy going and inquisitive. The only issues I have seen with both aspedities (black-headed pythons and womas) is in their adolescence they are voracious feeders and try to eat everything in front of them.
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