To some extend there is internal policing. In some cases it happens for economic reasons, with others it's for moral reasons.
Example: Desert ball python. If you look around you can find them for sale but there are not many, and they are super cheap due to the fertility problems with the females.
Example: Super motley boa. Put one up for sale in a Facebook classified group and you will get ripped to shreds in the comments, and Lord help you if you admit to pairing critters where you might produce one.
In neither of these instances do I see a reason for government involvement. The government already has plenty on its plate with investigating abuse and neglect, and unfortunately most animal control officials are just clueless when it comes to exotics. At the federal level it has to deal with invasive species, plus threatened or endangered species, investigate smugglers, etc.