20 Gallon is way to small for any larger fish.
A school of tetra's is a good suggestion(Congo or Emperors look very nice), they can be nippy though.
Rainbow fish or small to medium gourami pairs is another possibility.
A redtail shark is an unbelievably hardy minnow but, territorial so would be rough on tankmates in a 20 Gal tank.
Butterfly/Ram cichlids or Kribensis work in a 20 Gal as well.
Edit: brackish tanks allow things like Archerfish and they are just cool to watch. Messy but, cool.









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