I wouldn't say there is anything that is super emotional for me. However, one that just triggers memories of my childhood, and guys don't laugh, is "Close to You" by the Carpenters. I don't know why but it instantly conjurs memories of hanging at the lake with my family.

Someone mentioned Pearl Jam. I really like "Man of the Hour" which they used in the closing sequence of the movie Big Fish. When Vedder takes it down a notch, his voice is just haunting.

Some of the voices that came out of the Grunge era like Eddie Vedder, Chris Cornell, Layne Staley, Scott Weilland, Kurt Cobain were incredible. Sadly two are gone and Weilland almost didn't come through. But Vedder and Cornell still have great pipes.