The staining is indicative of illness or stress. A new environment could do it, allergies could do it, stress can do it.
The stain does take a little while to be cleaned off, so chances are he was sick/"in a stressful environment", and is doing better now. I suggest cleaning him with a wet rag and a little bit of soap. Monitor to see if he gets it again around his nose, eyes (he has a spot under his eyes now), sides, forearms.
If you want to know what a high white marking is, you can visit the AFRMA website gallery, in conjunction with the names or descriptions of the high white markings, and you will be able to see what they are exactly.
Your girl is a capped husky if I remember right.
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