Alll New World ratsnakes that I know of that have been successfully hybridized are in the genra Elaphe/Pantherophis, Lampropeltis, and Pituophis. Looking into it a little more I found that all these genera along with the Bogertophis genus and a couple other species have been studied using molecular systematics, and are believed to have evolved from the same branch of Elaphe. I would say the possiblilty of viable offspring between an animal from this group with some eurasian ratsnakes would be much more likely than with a corn and a rough or smooth greensnake. It would all depend on how much genetic drift has occured in the span of time since the gene pools were separated, and if there are any pre or post-zygotic barriers to successful fertilization and development. I'm sure someone will try in the future. I guess we'll just have to wait and see how compatible they really are once some one does.
-Evan
P.S. If anyone wants to read the paper in which the genus name Pantherophis was suggested, (Warning!!!, science content ahead ) here it is.